Heavy halogen impact on Raman water bands at high pressure: Implications for salinity estimations in fluid inclusions
Résumé
We present a new experimental dataset on the impact of the heavy halogens chlorine, bromine and iodine on the
Raman water bands concerning pressure and their concentration at room temperature. These experiments were
conducted at ambient temperature, with variations in halogen concentration and pressure ranging from 0 to 1.4
GPa.
The strength of the Raman water band shift change increases with the ionic size from chlorine, over bromine,
to iodine. Our experiments further demonstrate that increased pressure diminishes the impact of the halogen
shift change to a varying extent for each of the three halogens. This finding can have significant implications for
the salinity calculation of fluid inclusions in minerals such as quartz or olivine. Particularly in the low salinity
range, the concentration can be markedly underestimated if the pressure effect is neglected. For experiments in
diamond anvil cells involving halogens dissolved in water, the change in Raman water band shifts can serve
either as a new tool to monitor pressure, or to monitor the salinity.
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