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Solid-State Hierarchical Cyclodextrin-Based Supramolecular Polymer Constructed by Primary, Secondary, and Tertiary Azido Interactions

Abstract : The crystallization of a di-azido-alpha-cyclodextrin revealed a polymeric self-assembly involving a variety of azido-type interactions. The crystal arrangement relies on the cooperativity of a primary azido inclusion, a secondary azido-azido interaction involving an unprecedented distribution of canonical forms, and a tertiary azido-groove interaction. The second azido group brings in a major contribution to the supramolecular structure illustrating the benefit of a difunctionalization for the generation of hierarchy.
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https://hal.archives-ouvertes.fr/hal-01397903
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Submitted on : Wednesday, November 16, 2016 - 2:23:51 PM
Last modification on : Thursday, January 14, 2021 - 11:48:40 AM

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Mickaël Ménand, Segolene Adam Beaumais, Lise-Marie Chamoreau, Etienne Derat, Sébastien Blanchard, et al.. Solid-State Hierarchical Cyclodextrin-Based Supramolecular Polymer Constructed by Primary, Secondary, and Tertiary Azido Interactions. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2014, 53 (28), pp.7238-7242. ⟨10.1002/anie.201403578⟩. ⟨hal-01397903⟩

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