Influence of the nature of the reducible support on CO oxidation kinetics of supported Rhd+ catalysts: SnO2 versus Ce0.68Zr0.32O2 - Sorbonne Université Accéder directement au contenu
Article Dans Une Revue Topics in Catalysis Année : 2007

Influence of the nature of the reducible support on CO oxidation kinetics of supported Rhd+ catalysts: SnO2 versus Ce0.68Zr0.32O2

Céline Fontaine-Gautrelet
Laboratoire de Réactivité de Surface
CV
Cyril Thomas
Gérald Djéga-Mariadassou
  • Fonction : Auteur
Laboratoire de Réactivité de Surface

Résumé

CO-O2 kinetics was studied on Rh(0.3wt%)/SnO2 and compared with that reported previously on Rh/Ce0.68Zr0.32O2. The lower oxygen mobility on SnO2 and the stronger bonding of CO with the RhΔ+ sites of Rh/SnO2, are suggested to account for the lower CO oxidation activity of Rh/SnO2 compared with that reported on Rh/Ce0.68Zr0.32O2.

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Catalyse

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https://hal.science/hal-00157011

Soumis le : lundi 25 juin 2007-11:03:55

Dernière modification le : jeudi 11 avril 2024-13:08:12

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hal-00157011 , version 1 (25-06-2007)

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Céline Fontaine-Gautrelet, Cyril Thomas, Gérald Djéga-Mariadassou. Influence of the nature of the reducible support on CO oxidation kinetics of supported Rhd+ catalysts: SnO2 versus Ce0.68Zr0.32O2. Topics in Catalysis, 2007, 42-43, pp.363-366. ⟨10.1007/s11244-007-0206-y⟩. ⟨hal-00157011⟩

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