Oriented Gold Nanorods and Gold Nanorod Chains within Smectic Liquid Crystal Topological Defects

Abstract : We show that the use of oriented linear arrays of smectic A defects, the so-called smectic oily streaks, enables the orientation of gold nanorods (GNRs) for a large range of GNR diameters, ranging from 7 to 48 nm, and for various ligands. For the small GNRs it enables oriented end-to-end small chains of GNRs when the density is increased from around 2 GNRs/μm2 to around 6 GNRs/μm2. We have characterized the orientation of single GNRs by spectrophotometry and two-photon luminescence (TPL). A strongly anisotropic absorption of the composites and an on–off switching of GNR luminescence, both controlled by incident light polarization, are observed, revealing an orientation of the GNRs mostly parallel to the oily streaks. A more favorable trapping of GNRs by smectic dislocations with respect to ribbon-like defects is thus demonstrated. The dislocations appear to be localized at a specific localization, namely, the summit of rotating grain boundaries. Combining plasmonic absorption measurements, TPL measurements, and simulation of the plasmonic absorption, we show that the end-to-end GNR chains are both dimers and trimers, all parallel to each other, with a small gap between the coupled GNRs, on the order of 1.5 nm, thus associated with a large red-shift of 110 nm of the longitudinal plasmonic mode. A motion of the GNRs along the dislocations appears as a necessary ingredient for the formation of end-to-end GNR chains, the gap value being driven by the balance between the attracting van der Waals interactions and the steric repulsion between the GNRs and leading to interdigitation of the neighboring ligands. We thus obtain electromagnetic coupling of nanorods controlled by light polarization.
Document type :
Journal articles
Complete list of metadatas

https://hal.sorbonne-universite.fr/hal-01551477
Contributor : Gestionnaire Hal-Upmc <>
Submitted on : Friday, June 30, 2017 - 12:17:34 PM
Last modification on : Friday, May 24, 2019 - 5:29:30 PM
Long-term archiving on : Monday, January 22, 2018 - 9:18:29 PM

File

Rozic_2017_Oriented_Gold.pdf
Files produced by the author(s)

Identifiers

Citation

Brigita Rožič, Jérôme Fresnais, Celine Molinaro, Joseph Calixte, Shivakumar Umadevi, et al.. Oriented Gold Nanorods and Gold Nanorod Chains within Smectic Liquid Crystal Topological Defects. ACS Nano, American Chemical Society, 2017, 11 (7), pp.6728-6738. ⟨10.1021/acsnano.7b01132⟩. ⟨hal-01551477⟩

Share

Metrics

Record views

1413

Files downloads

265