Metal–organic frameworks meet polymer brushes: enhanced crystalline film growth induced by macromolecular primers

Abstract : We used poly-(3-sulfopropylmethacrylate) brushes as macromolecular 3D primers to promote heterogeneous nucleation and growth of archetypal ZIF-8 MOF thin films. The enhancement can be understood in terms of a high preconcentration of Zn2+ ions in the polymer brush; this leads to a rapid increase of nucleation sites in the primer.
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Materials chemistry frontiers, Royal Society of Chemistry, 2017, 2017 (1), pp.2256-2260 〈10.1039/C7QM00235A〉
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Soumis le : lundi 23 octobre 2017 - 15:40:37
Dernière modification le : vendredi 31 août 2018 - 09:08:42

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Matías Rafti, Juan A. Allegretto, Gustavo M. Segovia, Jimena S. Tuninetti, Juan M. Giussi, et al.. Metal–organic frameworks meet polymer brushes: enhanced crystalline film growth induced by macromolecular primers. Materials chemistry frontiers, Royal Society of Chemistry, 2017, 2017 (1), pp.2256-2260 〈10.1039/C7QM00235A〉. 〈hal-01592683〉

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