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Metal–organic frameworks meet polymer brushes: enhanced crystalline film growth induced by macromolecular primers

Abstract : We used poly-(3-sulfopropylmethacrylate) brushes as macromolecular 3D primers to promote heterogeneous nucleation and growth of archetypal ZIF-8 MOF thin films. The enhancement can be understood in terms of a high preconcentration of Zn2+ ions in the polymer brush; this leads to a rapid increase of nucleation sites in the primer.
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Submitted on : Monday, October 23, 2017 - 3:40:37 PM
Last modification on : Friday, October 30, 2020 - 2:40:03 PM

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Matías Rafti, Juan A. Allegretto, Gustavo M. Segovia, Jimena S. Tuninetti, Juan M. Giussi, et al.. Metal–organic frameworks meet polymer brushes: enhanced crystalline film growth induced by macromolecular primers. Materials Chemistry Frontiers, Royal Society of Chemistry, 2017, 2017 (1), pp.2256-2260 ⟨10.1039/C7QM00235A⟩. ⟨hal-01592683⟩

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