L. Bertrand, Development and trends in synchrotron studies of ancient and historical materials, Phys. Rep, vol.519, issue.2, pp.51-96, 2012.
URL : https://hal.archives-ouvertes.fr/hal-02130576

L. Bertrand, M. Thoury, and E. Anheim, Ancient materials specificities for their synchrotron examination and insights into their epistemological implications, J. Cult. Heritage, vol.14, issue.4, pp.277-289, 2013.
URL : https://hal.archives-ouvertes.fr/hal-01136065

L. Bertrand, Emerging approaches in synchrotron studies of materials from cultural and natural history collections, Top. Curr. Chem, vol.374, issue.1, p.7, 2016.
URL : https://hal.archives-ouvertes.fr/hal-01388790

K. Janssens, Non-invasive and non-destructive examination of artistic pigments, paints, and paintings by means of X-ray methods, Top. Curr. Chem, vol.374, issue.6, p.81, 2016.

M. Cotte, Synchrotron-based X-ray absorption spectroscopy for art conservation: looking back and looking forwards, Acc. Chem. Res, vol.43, issue.6, pp.705-714, 2010.

M. Alfeld, A mobile instrument for in situ scanning macro-XRF investigation of historical paintings, J. Anal. At. Spectrom, vol.28, issue.5, pp.760-767, 2013.

J. Dik, Visualization of a lost painting by Vincent van Gogh visualized by synchrotron radiation based X-ray fluorescence elemental mapping, Anal. Chem, vol.80, pp.6436-6442, 2008.

W. De-nolf, High energy X-ray powder diffraction for the imaging of (hidden) paintings, J. Anal. At. Spectrom, vol.26, issue.5, pp.910-916, 2011.

F. Vanmeert, Highly-specific chemical mapping by macroscopic X-ray powder diffraction (MA-XRPD) of Van Gogh's Sunflowers allows to identify areas with higher degradation risk, Angew. Chem. Int. Ed, vol.25, pp.7418-7422, 2018.

G. E. Ice, J. D. Budai, and J. W. Pang, The race to x-ray microbeam and nanobeam science, Science, vol.334, issue.6060, pp.1234-1239, 2011.

K. Yamauchi, Figuring with subnanometer-level accuracy by numerically controlled elastic emission machining, Rev. Sci. Instrum, vol.73, issue.11, pp.4028-4033, 2002.

H. Mimura, Breaking the 10 nm barrier in hard-X-ray focusing, Nat. Phys, vol.6, issue.2, p.122, 2010.

J. C. Da and . Silva, Efficient concentration of high-energy x-rays for diffraction-limited imaging resolution, Optica, vol.4, issue.5, pp.492-495, 2017.
URL : https://hal.archives-ouvertes.fr/hal-01691891

A. Snigirev, A compound refractive lens for focusing high-energy X-rays, Nature, vol.384, issue.6604, p.49, 1996.

J. Vila-comamala, Zone-doubled Fresnel zone plates for high-resolution hard X-ray full-field transmission microscopy, J. Synchrotron Radiat, vol.19, issue.5, pp.705-709, 2012.

E. D. Fabrizio, High-efficiency multilevel zone plates for keV X-rays, Nature, vol.401, issue.6756, p.895, 1999.

H. Kang, Nanometer linear focusing of hard x rays by a multilayer Laue lens, Phys. Rev. Lett, vol.96, issue.12, p.127401, 2006.

H. C. Kang, Focusing of hard x-rays to 16 nanometers with a multilayer Laue lens, Appl. Phys. Lett, vol.92, issue.22, p.221114, 2008.

E. Nazaretski, Performance and characterization of the prototype nm-scale spatial resolution scanning multilayer Laue lenses microscope, Rev. Sci. Instrum, vol.84, issue.3, p.33701, 2013.

M. Schreiner, M. Melcher, and K. Uhlir, Scanning electron microscopy and energy dispersive analysis: applications in the field of cultural heritage, Anal. Bioanal. Chem, vol.387, issue.3, pp.737-747, 2007.

A. N. Shugar and J. L. Mass, Handheld XRF for Art and Archaeology, vol.3, 2012.

K. Janssens, Use of microscopic XRF for non-destructive analysis in art and archaeometry, X-Ray Spectrom, vol.29, issue.1, pp.73-91, 2000.

M. Alfeld, Visualizing the 17th century underpainting in Portrait of an Old Man by Rembrandt van Rijn using synchrotron-based scanning macro-XRF, Appl. Phys. A, vol.111, issue.1, pp.157-164, 2013.

E. Brun, Revealing metallic ink in Herculaneum papyri, Proc. Natl. Acad. Sci, vol.113, issue.14, pp.3751-3754, 2016.
DOI : 10.1073/pnas.1519958113

URL : http://www.pnas.org/content/113/14/3751.full.pdf

M. Cotte, Applications of synchrotron-based micro-imaging techniques to the chemical analysis of ancient paintings, J. Anal. At. Spectrom, vol.23, pp.820-828, 2008.

M. Cotte, Synchrotron-based X-ray spectromicroscopy used for the study of an atypical micrometric pigment in 16th century paintings, Anal. Chem, vol.79, pp.6988-6994, 2007.

S. Cersoy, Identifying and quantifying amorphous and crystalline content in complex powdered samples: application to archaeological carbon blacks, J. Appl. Crystallogr, vol.49, issue.2, pp.585-593, 2016.
DOI : 10.1107/s1600576716003551

URL : https://hal.archives-ouvertes.fr/hal-01355748

F. Casadio and V. Rose, High-resolution fluorescence mapping of impurities in historical zinc oxide pigments: hard X-ray nanoprobe applications to the paints of Pablo Picasso, Appl. Phys. A, vol.111, issue.1, pp.1-8, 2013.

R. P. Winarski, A hard X-ray nanoprobe beamline for nanoscale microscopy, J. Synchrotron Radiat, vol.19, issue.6, pp.1056-1060, 2012.
DOI : 10.1107/s0909049512036783

URL : https://doi.org/10.1107/s0909049512036783

T. Ungár, Revealing the powdering methods of black makeup in ancient Egypt by fitting microstructure based Fourier coefficients to the whole x-ray diffraction profiles of galena, J. Appl. Phys, vol.91, issue.4, pp.2455-2465, 2002.

V. Gonzalez, Synchrotron-based high angle resolution and high lateral resolution X-ray diffraction: revealing lead white pigment qualities in old masters paintings, Anal. Chem, vol.89, issue.24, pp.13203-13211, 2017.
DOI : 10.1021/acs.analchem.7b02949

URL : https://hal.sorbonne-universite.fr/hal-01651814/file/Gonzalez%20et%20al.%20-%202017%20-%20Synchrotron-based%20high%20angle%20resolution%20and%20high%20l.pdf

L. Monico, The degradation process of lead chromate in paintings by Vincent van Gogh studied by means of spectromicroscopic methods. Part III: Synthesis, characterization and detection of different crystal forms of the chrome yellow pigment, Anal. Chem, vol.85, issue.2, pp.851-859, 2013.

L. Monico, The degradation process of lead chromate in paintings by Vincent van Gogh studied by means of spectromicroscopic methods. Part IV: Artificial ageing of model samples of co-precipitates of lead chromate and lead sulfate, Anal. Chem, vol.85, issue.2, pp.860-867, 2013.

M. Radepont, Thermodynamic and experimental study of the degradation of the red pigment mercury sulfide, J. Anal. At. Spectrom, vol.30, issue.3, pp.599-612, 2015.

F. Da-pieve, Casting light on the darkening of colors in historical paintings, Phys. Rev. Lett, vol.111, issue.20, p.208302, 2013.

W. Anaf, K. Janssens, and K. D. Wael, Formation of metallic mercury during photodegradation/photodarkening of ?-HgS: electrochemical evidence, Angew. Chem, vol.125, issue.48, pp.12800-12803, 2013.

P. Bleuet, Probing the structure of heterogeneous diluted materials by diffraction tomography, Nat. Mater, vol.7, issue.6, pp.468-472, 2008.
URL : https://hal.archives-ouvertes.fr/hal-00188490

F. Vanmeert, G. Van-der-snickt, and K. Janssens, Plumbonacrite identified by X-ray powder diffraction tomography as a missing link during degradation of red lead in a Van Gogh painting, Angew. Chem, vol.54, issue.12, pp.3678-3681, 2015.

P. A. Lynch, Application of white-beam X-ray microdiffraction for the study of mineralogical phase identification in ancient Egyptian pigments, J. Appl. Crystallogr, vol.40, issue.6, pp.1089-1096, 2007.

Z. Liu, Influence of Taoism on the invention of the purple pigment used on the Qin terracotta warriors, J. Archaeol. Sci, vol.34, issue.11, pp.1878-1883, 2007.

C. Dejoie, Complementary use of monochromatic and white-beam X-ray micro-diffraction for the investigation of ancient materials, J. Appl. Crystallogr, vol.48, issue.5, pp.1522-1533, 2015.
URL : https://hal.archives-ouvertes.fr/hal-01760144

F. Farges and M. Cotte, X-ray absorption spectroscopy and cultural heritage: highlights and perspectives, X-Ray Absorption and X-Ray Emission Spectroscopy: Theory and Applications, pp.609-636, 2016.
DOI : 10.1002/9781118844243.ch21

K. Janssens and M. Cotte, The use of XAS and related methods in Cultural Heritage investigations, International Tables for Crystallography, vol.I

C. Gervais, Time resolved XANES illustrates a substrate-mediated redox process in Prussian blue cultural heritage materials, J. Phys. Conf. Ser, 2016.

S. Lahlil, Synthesis of calcium antimonate nano-crystals by the 18th dynasty Egyptian glassmakers, Appl. Phys. A, vol.98, issue.1, pp.1-8, 2010.
URL : https://hal.archives-ouvertes.fr/hal-00646200

S. Lahlil, New insight on the in situ crystallization of calcium antimonate opacified glass during the Roman period, Appl. Phys. A, vol.100, issue.3, pp.683-692, 2010.

S. Lahlil, Synthesizing lead antimonate in ancient and modern opaque glass, J. Anal. At. Spectrom, vol.26, issue.5, pp.1040-1050, 2011.
URL : https://hal.archives-ouvertes.fr/hal-00646060

F. Mirambet, Synchrotron radiation contribution to the study of aluminium corrosion layers of air and space museum aircrafts for their preservation, J. Anal. At. Spectrom, vol.31, issue.8, pp.1631-1637, 2016.

K. Keune, Analytical imaging studies of the migration of degraded orpiment, realgar, and emerald green pigments in historic paintings and related conservation issues, Heritage Sci, vol.4, issue.1, p.10, 2016.

K. Keune, Tracking the transformation and transport of arsenic sulfide pigments in paints: synchrotron-based X-ray micro-analyses, J. Anal. At. Spectrom, vol.30, issue.3, pp.813-827, 2015.

G. Nuyts, Micro-XANES study on Mn browning: use of quantitative valence state maps, J. Anal. At. Spectrom, vol.30, issue.3, pp.642-650, 2015.

M. Vermeulen, Visualization of As(III) and As(V) distributions in degraded paint micro-samples from Baroque-and Rococo-era paintings, J. Anal. At. Spectrom, vol.31, issue.9, pp.1913-1921, 2016.

. Jacobsen, Soft X-ray spectroscopy from image sequences with sub-100 nm spatial resolution, J. Microsc, vol.197, issue.2, pp.173-184, 2000.

M. Obst and G. Schmid, 3D chemical mapping: application of scanning transmission (soft) X-ray microscopy (STXM) in combination with angle-scan tomography in bio-, geo-, and environmental sciences, Electron Microscopy: Methods and Protocols, pp.757-781, 2014.

S. Bernard, Ultrastructural and chemical study of modern and fossil sporoderms by scanning transmission X-ray microscopy (STXM), Rev. Palaeobot. Palynol, vol.156, issue.1, pp.248-261, 2009.

A. Michelin, Investigation at the nanometre scale on the corrosion mechanisms of archaeological ferrous artefacts by STXM, J. Anal. At. Spectrom, vol.28, issue.1, pp.59-66, 2013.

V. Rouchon and S. Bernard, Mapping iron gall ink penetration within paper fibres using scanning transmission X-ray microscopy, J. Anal. At. Spectrom, vol.30, issue.3, pp.635-641, 2015.
URL : https://hal.archives-ouvertes.fr/hal-01433138

F. Meirer, Full-field XANES analysis of Roman ceramics to estimate firing conditions-a novel probe to study hierarchical heterogeneous materials, J. Anal. At. Spectrom, vol.28, issue.12, pp.1870-1883, 2013.
URL : https://hal.archives-ouvertes.fr/hal-01431729

I. Cianchetta, Evidence for an unorthodox firing sequence employed by the Berlin painter: deciphering ancient ceramic firing conditions through high-resolution material characterization and replication, J. Anal. At. Spectrom, vol.30, pp.666-676, 2015.
URL : https://hal.archives-ouvertes.fr/hal-01572914

P. Dillmann, L. Bellot-gurlet, and I. Nenner, Nanoscience and Cultural Heritage, 2016.
URL : https://hal.archives-ouvertes.fr/cea-01330503

F. Casadio, Electron energy loss spectroscopy elucidates the elusive darkening of zinc potassium chromate in Georges Seurat's A Sunday on La Grande Jatte-1884, Anal. Bioanal. Chem, pp.1-12, 2010.

H. Tan, Nanoscale investigation of the degradation mechanism of a historical chrome yellow paint by quantitative electron energy loss spectroscopy mapping of chromium species, Angew. Chem. Int. Ed, vol.52, issue.43, pp.11360-11363, 2013.

M. Derrick, D. Stulik, and J. M. Landry, Infrared spectroscopy in conservation science, Scientific Tools for Conservation, The Guetty Conservation Institute, p.235, 1999.

S. Prati, New frontiers in application of FTIR microscopy for characterization of cultural heritage materials, Top. Curr. Chem, vol.374, issue.3, p.26, 2016.

M. Cotte, Recent applications and current trends in cultural heritage science using synchrotron-based Fourier transform infrared microspectroscopy, C. R. Physique, vol.10, issue.7, pp.590-600, 2009.

G. Latour, Correlative nonlinear optical microscopy and infrared nanoscopy reveals collagen degradation in altered parchments, Sci. Rep, vol.6, p.26344, 2016.
URL : https://hal.archives-ouvertes.fr/hal-01321012

D. Kurouski, Tip-enhanced Raman spectroscopy (TERS) for in situ identification of indigo and iron gall ink on paper, J. Am. Chem. Soc, vol.136, issue.24, pp.8677-8684, 2014.

B. Marino, Imaging Tof-SIMS and NanoSIMS studies of berite-celestite particles in grounds from paintings by van Gogh, in: e-Preservation Science, Proceedings of 2006 AIC Annual Conference, vol.3, pp.41-50, 2006.

J. Sanyova, Unexpected materials in a Rembrandt painting characterized by high spatial resolution cluster-TOF-SIMS imaging, Anal. Chem, vol.83, issue.3, pp.753-760, 2011.
URL : https://hal.archives-ouvertes.fr/hal-00572516

P. Tafforeau, Applications of X-ray synchrotron microtomography for non-destructive 3D studies of paleontological specimens, Appl. Phys. A, vol.83, issue.2, pp.195-202, 2006.
URL : https://hal.archives-ouvertes.fr/hal-00174890

M. Jacot-guillarmod, Degradation mechanisms of reinforcing iron rebars in monuments: the role of multiscale porosity in the formation of corrosion products investigated by X-ray tomography, J. Anal. At. Spectrom, vol.30, issue.3, pp.580-587, 2015.
URL : https://hal.archives-ouvertes.fr/insu-01141774

E. S. Ferreira, 3D synchrotron x-ray microtomography of paint samples, Proceedings of SPIE-The International Society for Optical Engineering, 2009.

E. S. Ferreira, Study of the mechanism of formation of calcium soaps in an early 20th century easel painting with correlative 2D and 3D microscopy, 2011.

C. Gervais, Characterization of porosity in a 19th century painting ground by synchrotron radiation X-ray tomography, Appl. Phys. A, Mater. Sci. Process, vol.111, issue.1, pp.31-38, 2013.

J. C. Silva, High-energy cryo x-ray nano-imaging at the ID16A beamline of ESRF, 2017.

A. Genty-vincent, Blanching of paint and varnish layers in easel paintings: contribution to the understanding of the alteration, Appl. Phys. A, vol.121, issue.3, pp.779-788, 2015.

A. Genty-vincent, Four-flux model of the light scattering in porous varnish and paint layers: towards understanding the visual appearance of altered blanched easel oil paintings, Appl. Phys. A, vol.123, issue.7, p.473, 2017.

A. Genty-vincent, Blanching of paint and varnish layers: from the characterization to the development of an efficient conservation treatment

E. Pouyet, Thin-sections of painting fragments: opportunities for combined synchrotron-based micro-spectroscopic techniques, Heritage Sci, vol.3, issue.1, pp.1-16, 2015.

E. Pouyet, Preparation of thin-sections of painting fragments: classical and innovative strategies, Anal. Chim. Acta, vol.822, pp.51-59, 2014.

M. Cotte, The ID21 X-ray and infrared microscopy beamline at the ESRF: status and recent applications to artistic materials, J. Anal. At. Spectrom, vol.32, pp.477-493, 2017.
URL : https://hal.archives-ouvertes.fr/hal-01935489

L. Monico, Full spectral XANES imaging using the Maia detector array as a new tool for the study of the alteration process of chrome yellow pigments in paintings by Vincent van Gogh, J. Anal. At. Spectrom, vol.30, issue.3, pp.613-626, 2015.

L. Bertrand, Mitigation strategies for radiation damage in the analysis of ancient materials, TrAC, Trends Anal. Chem, vol.66, pp.128-145, 2015.
URL : https://hal.archives-ouvertes.fr/hal-02129557

L. Lemelle, Analytical requirements for quantitative X-ray fluorescence nano-imaging of metal traces in solid samples, TrAC, Trends Anal. Chem, vol.91, pp.104-111, 2017.
URL : https://hal.archives-ouvertes.fr/hal-02358945