Directed Organization of Platinum Nanocrystals through Organic Supramolecular Nanoporous Templates
Abstract
We propose a novel approach to trap 2 nm Pt nanocrystals using nanoporous two-dimensional supramolecular networks for cavity-confined host-guest recognition process. This will be achieved by taking advantage of two features of supramolecular self-assembly at surfaces. First, its capability to allow to the formation of complex 2D architectures, more particularly nanoporous networks, through non-covalent interactions between organic molecular building-blocks. Second, the ability of the nanopores to selectively host and immobilize a large variety of guest species. In this paper, for the first time, we will use isotropic honeycomb networks and anisotropic linear porous supramolecular networks to host 2nm Pt nanocrystals.
Domains
Chemical Sciences
Origin : Files produced by the author(s)
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