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Directed Organization of Platinum Nanocrystals through Organic Supramolecular Nanoporous Templates

Farid Kameche 1 Alice Six 2 Fabrice Charra 3 Anh-Tu Ngo 1 Fabrice Mathevet 4 Caroline Salzemann 1 David Kreher 4 Imad Arfaoui 1 André-Jean Attias 4 Petit Christophe
3 LEPO - Laboratoire d'Electronique et nanoPhotonique Organique
SPEC - UMR3680 - Service de physique de l'état condensé, IRAMIS - Institut Rayonnement Matière de Saclay
4 LCP - Chimie des polymères
UPMC - Université Pierre et Marie Curie - Paris 6, IPCM - Institut Parisien de Chimie Moléculaire, CNRS - Centre National de la Recherche Scientifique : UMR7610
Abstract : We propose a novel approach to trap 2 nm Pt nanocrystals using nanoporous two-dimensional supramolecular networks for cavity-confined host−guest recognition process. This will be achieved by taking advantage of two features of supramolecular self-assembly at surfaces: First, its capability to allow the formation of complex 2D architectures, more particularly, nanoporous networks, through non-covalent interactions between organic molecular building-blocks; second, the ability of the nanopores to selectively host and immobilize a large variety of guest species. In this paper, for the first time, we will use isotropic honeycomb networks and anisotropic linear porous supramolecular networks to host 2 nm Pt nanocrystals.
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Farid Kameche, Alice Six, Fabrice Charra, Anh-Tu Ngo, Fabrice Mathevet, et al.. Directed Organization of Platinum Nanocrystals through Organic Supramolecular Nanoporous Templates. Langmuir, American Chemical Society, 2017, 33 (44), pp.12759-12765. ⟨10.1021/acs.langmuir.7b01893⟩. ⟨hal-01978592⟩



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