Modulation of catalyst enantioselectivity through reversible assembly of supramolecular helices
Abstract
A multi-configurable catalyst, for which the degree of enantioinduction in successive reactions is varied between 6% ee and 52% ee, is achieved by supporting copper centres at the periphery of supramolecular helices. Precise characterization of the co-assemblies corroborates the relation between helix length and catalyst selectivity.
Domains
Catalysis
Fichier principal
Chem.Commun., 2019, 2162.pdf (1.07 Mo)
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Chem.Commun., 2019, 2162 si.pdf (2.86 Mo)
Télécharger le fichier
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