Modulation of catalyst enantioselectivity through reversible assembly of supramolecular helices
Résumé
A multi-configurable catalyst, for which the degree of enantioinduction in successive reactions is varied between 6% ee and 52% ee, is achieved by supporting copper centres at the periphery of supramolecular helices. Precise characterization of the co-assemblies corroborates the relation between helix length and catalyst selectivity.
Domaines
Catalyse
Fichier principal
Chem.Commun., 2019, 2162.pdf (1.07 Mo)
Télécharger le fichier
Chem.Commun., 2019, 2162 si.pdf (2.86 Mo)
Télécharger le fichier
| Origine | Fichiers produits par l'(les) auteur(s) |
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