Carbon‐Nanotube‐Supported Copper Polyphthalocyanine for Efficient and Selective Electrocatalytic CO 2 Reduction to CO - Sorbonne Université Accéder directement au contenu
Article Dans Une Revue ChemSusChem Année : 2019

Carbon‐Nanotube‐Supported Copper Polyphthalocyanine for Efficient and Selective Electrocatalytic CO 2 Reduction to CO

Résumé

Electroreduction of CO2 to CO is one of the simplest ways to valorise CO2 as a source of carbon. Herein, a cheap, robust, Cu-based hybrid catalyst consisting of a polymer of Cu phthalocyanine coated on carbon nanotubes, which proved to be selective for CO production (80 % faradaic yield) at relatively low overpotentials, was developed. Polymerisation of Cu phthalocyanine was shown to have a drastic effect on the selectivity of the reaction because molecular Cu phthalocyanine was instead selective for proton reduction under the same conditions. Although the material only showed isolated Cu sites in phthalocyanine-like CuN4 coordination, in situ and operando X-ray absorption spectroscopy showed that, under operating conditions, the Cu atoms were fully converted to Cu nanoparticles, which were likely the catalytically active species. Interestingly, this restructuring of the metal sites was reversible.

Domaines

Chimie
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Dates et versions

hal-02408905 , version 1 (13-12-2019)

Identifiants

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Dilan Karapinar, Andrea Zitolo, Tran Ngoc Huan, Sandrine Zanna, Dario Taverna, et al.. Carbon‐Nanotube‐Supported Copper Polyphthalocyanine for Efficient and Selective Electrocatalytic CO 2 Reduction to CO. ChemSusChem, 2019, ⟨10.1002/cssc.201902859⟩. ⟨hal-02408905⟩
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