Thermoresponsive dynamic BAB block copolymer networks synthesized by aqueous PISA in one-pot - Sorbonne Université Accéder directement au contenu
Article Dans Une Revue Polymer Chemistry Année : 2021

Thermoresponsive dynamic BAB block copolymer networks synthesized by aqueous PISA in one-pot

Résumé

We report a straightforward process to produce well-defined dynamic networks of associative BAB triblock copolymers through two successive polymerization steps conducted in one-pot and exclusively in water. The copolymers are composed of a hydrophilic poly(N,N-dimethylacrylamide) A block extended in a typical RAFT-PISA dispersion formulation with two lateral associative statistical poly(diacetone acrylamide-co-N,N-dimethylacrylamide) B blocks. The viscosity of the samples is strongly modified by the N,N-dimethylacrylamide (DMAc) content in the B block. This is attributed to the formation of a transient network for which the exchange dynamics of the B blocks between micelles and/or the number of bridges within the network depend on the DMAc content. Rheology analyses showed that transient networks are formed that exhibit a thermoresponsive behavior with a maximum viscosity as a function of temperature, presumably caused by a maximum of bond lifetime and/or number of elastically active chains.

Domaines

Polymères
Fichier principal
Vignette du fichier
Biais et al. - 2021 - Thermoresponsive dynamic BAB block copolymer netwo.pdf (1.42 Mo) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)

Dates et versions

hal-03273634 , version 1 (29-06-2021)

Identifiants

Citer

Pauline Biais, Marie Engel, Olivier Colombani, Taco Nicolaï, François Stoffelbach, et al.. Thermoresponsive dynamic BAB block copolymer networks synthesized by aqueous PISA in one-pot. Polymer Chemistry, 2021, 12 (7), pp.1040-1049. ⟨10.1039/D0PY01424A⟩. ⟨hal-03273634⟩
55 Consultations
112 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More