Article Dans Une Revue Molecular Physics Année : 1985

Potential of mean force on an ion near a wall in presence of a molecular solvent

Résumé

The potential of mean force is calculated for one ion immersed in a fluid of dipolar hard spheres in the vicinity of a neutral hard wall. The molecular nature of the solvent induces significant deviations from the primitive model result. A pure MSA treatment would only give the potential of mean force associated with the hard sphere fluid. The present theory automatically includes the existence of the image potential.

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Chimie
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Dates et versions

hal-04662875 , version 1 (26-07-2024)

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Jean-Pierre Badiali, M.L. Rosinberg, V. Russier. Potential of mean force on an ion near a wall in presence of a molecular solvent. Molecular Physics, 1985, 56 (1), pp.105-114. ⟨10.1080/00268978500102201⟩. ⟨hal-04662875⟩
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