Article Dans Une Revue Journal of electroanalytical chemistry and interfacial electrochemistry Année : 1984

Computer simulation of potentiostatic current-time transients for nickel electrocrystallization

Résumé

A stepwise computer model is presented for the potentiostatic current-time transient response of hemispherical centres nucleation and the radial growth mechanism. A general time-dependent nucleation law is considered and a particular attention is devoted to the effects of the ohmic drop on the transient responses and onto the growing centres number. Computed data are compared to experimental transient curves and to TEM micrographs obtained in the case of nickel electrocrystallization onto vitreous carbon.

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Chimie

Dates et versions

hal-04665649 , version 1 (31-07-2024)

Identifiants

Citer

E. Trevisan-Souteyrand, Georges Maurin, D. Mercier. Computer simulation of potentiostatic current-time transients for nickel electrocrystallization. Journal of electroanalytical chemistry and interfacial electrochemistry, 1984, 161 (1), pp.17-30. ⟨10.1016/S0022-0728(84)80246-6⟩. ⟨hal-04665649⟩
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