Article Dans Une Revue Journal of electroanalytical chemistry and interfacial electrochemistry Année : 1983

A microscopic model for the liquid metal-ionic solution interface

M.L. Rosinberg
  • Fonction : Auteur
F. Vericat
  • Fonction : Auteur
L. Blum
  • Fonction : Auteur

Résumé

A microscopic model for the metal-solution interface is presented, which, for the first time, includes both a non-ideal treatment of the metal and a molecular model for the solution side. The metal is described by a jellium model including electron-ion pseudo-potential. The solution is treated as a mixture of hard spheres with point dipoles (solvent molecules) or point charges (ions). The statistical mechanics is solved using mean spherical approximation. No a priori separation is introduced between compact and diffuse layers. A simplified version of the model is applied to the case of Hg-DMSO systems.

Domaines

Chimie

Dates et versions

hal-04693965 , version 1 (11-09-2024)

Identifiants

Citer

Jean-Pierre Badiali, M.L. Rosinberg, F. Vericat, L. Blum. A microscopic model for the liquid metal-ionic solution interface. Journal of electroanalytical chemistry and interfacial electrochemistry, 1983, 158 (2), pp.253-267. ⟨10.1016/S0022-0728(83)80611-1⟩. ⟨hal-04693965⟩
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