Selective hydrodechlorination of 1,2-dichloroethane on NiSiBEA zeolite catalyst: Influence of the preparation procedure on a high dispersion of Ni centers - Sorbonne Université Access content directly
Journal Articles Microporous and Mesoporous Materials Year : 2013

Selective hydrodechlorination of 1,2-dichloroethane on NiSiBEA zeolite catalyst: Influence of the preparation procedure on a high dispersion of Ni centers

Abstract

NixSiBEA zeolites (x = 1-2 Ni wt.%) were prepared by a two-steps postsynthesis method which consists of (1) creation of vacant T-sites by dealumination of tetraethylammonium BEA zeolite with nitric acid and then (2) impregnation of resulting SiBEA zeolite with an aqueous solution of Ni(NO3)2, following a drying (333 K) of as prepared NixSiBEA. The calcination of NixSiBEA at 773 K for 3 h in air leads to formation of CNixSiBEA with an isolated pseudo-tetrahedral Ni(II) species incorporated in BEA framework as evidenced by combined use of XRD, DR UV-vis, XPS and TPR. The reduction of C-NixSiBEA (873 K, 3 h in flowing 10% H2/Ar) leads to formation of red-C-NixSiBEA with a very high dispersion of nickel (>65%) measured by oxygen chemisorption. The red-C-NixSiBEA catalysts were active in hydrodechlorination of chlorinated volatile organic compound (1,2-dichloroethane) at relatively low reaction temperatures (523-543 K) with a very high selectivity (90%) into desired product, ethylene. TPH experiments have shown that after hydrodechlorination of 1,2-dichloroethane a very little amount of carbonaceous and chlorine-containing species are present on spent NixSiBEA zeolite catalysts.

Domains

Catalysis

Dates and versions

hal-00811551 , version 1 (10-04-2013)

Identifiers

Cite

R. Baran, I.I. Kamińska, A. Śrębowata, S. Dzwigaj. Selective hydrodechlorination of 1,2-dichloroethane on NiSiBEA zeolite catalyst: Influence of the preparation procedure on a high dispersion of Ni centers. Microporous and Mesoporous Materials, 2013, 169, pp.120-127. ⟨10.1016/j.micromeso.2012.11.005⟩. ⟨hal-00811551⟩
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