Skip to Main content Skip to Navigation
Journal articles

Surface charge of acidic sophorolipid micelles: effect of base and time

Abstract : Acidic sophorolipids, SL–COOH, bio-derived glycolipids, are known to form micelles whose interactions vary as a function of pH. Upon partial ionization of the COOH group, intermicellar interactions take place. Here, we explore the nature of these interactions by using small angle neutron scattering (SANS) on SL–COOH solutions to which increasing amounts of NaOH are added. The effect of the nature of the base is also explored by replacing NaOH with aqueous NH3, KOH and Ca(OH)2. Time effects up to 36 days are also discussed. All SANS data have been successfully fitted using an appropriate model of core–shell prolate ellipsoids of revolution with an interaction potential, U(r), which combines hard-sphere and screened Coulomb (described by a repulsive Yukawa potential) potentials. Modelling quantifies the effect of the base in terms of micellar size, effective surface charge and interfacial hydration, thus showing the possibility of tuning them at will.
Document type :
Journal articles
Complete list of metadatas

Cited literature [21 references]  Display  Hide  Download

https://hal.sorbonne-universite.fr/hal-01457010
Contributor : Gestionnaire Hal-Upmc <>
Submitted on : Monday, February 6, 2017 - 10:59:32 AM
Last modification on : Friday, October 30, 2020 - 2:40:03 PM
Long-term archiving on: : Sunday, May 7, 2017 - 12:54:51 PM

File

10.1039-c3sm50160d.pdf
Files produced by the author(s)

Identifiers

Citation

Niki Baccile, Jan Skov Pedersen, Gerard Pehau-Arnaudet, Inge N. A. van Bogaert. Surface charge of acidic sophorolipid micelles: effect of base and time . Soft Matter, Royal Society of Chemistry, 2013, 9, pp.4911-4922 ⟨10.1039/C3SM50160D⟩. ⟨hal-01457010⟩

Share

Metrics

Record views

471

Files downloads

923