Skip to Main content Skip to Navigation
Journal articles

Insights into Li+ , Na+ , and K+ Intercalation in Lepidocrocite-Type Layered TiO 2 Structures

Abstract : A lamellar lepidocrocite-type titanate structure with ∼25% Ti4+ vacancies was recently synthesized, and it showed potential for use as an electrode in rechargeable lithium-ion batteries. In addition to lithium, we explore this material’s ability to accommodate other monovalent ions with greater natural abundance (e.g., sodium and potassium) in order to develop lower-cost alternatives to lithium-ion batteries constructed from more widely available elements. Galvanostatic discharge/charge curves for the lepidocrocite material indicate that increasing the ionic radius of the monovalent ion results in a deteriorating performance of the electrode. Using first-principles electronic structure calculations, we identify the relaxed geometries of the structure while varying the placement of the ion in the structure. We then use these geometries to compute the energy of formations. Additionally, we determine that all ions are favorable in the structure, but interlayer positions are preferred compared to vacancy positions. We also conclude that the exchange between the interlayer and vacancy positions is a process that involves the interaction between interlayer water and surface hydroxyl groups next to the titanate layer. We observe a cooperative effect between structural water and OH groups to assist alkali ions to move from the interlayer to the vacancy site. Thus, the as-synthesized lepidocrocite serves as a prototypical structure to investigate the migration mechanism of ions within a confined space along with the interaction between water molecules and the titanate framework.
Document type :
Journal articles
Complete list of metadata

Cited literature [39 references]  Display  Hide  Download
Contributor : Gestionnaire Hal-Upmc <>
Submitted on : Friday, February 21, 2020 - 3:08:01 PM
Last modification on : Monday, April 19, 2021 - 8:56:16 AM
Long-term archiving on: : Friday, May 22, 2020 - 3:35:56 PM


Reeves et al. - 2018 - Insight...
Files produced by the author(s)



Kyle Reeves, Jiwei Ma, Mika Fukunishi, Mathieu Salanne, Shinichi Komaba, et al.. Insights into Li+ , Na+ , and K+ Intercalation in Lepidocrocite-Type Layered TiO 2 Structures. ACS Applied Energy Materials, ACS, 2018, 1 (5), pp.2078 - 2086. ⟨10.1021/acsaem.8b00170⟩. ⟨hal-01920966⟩



Record views


Files downloads