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Basic concepts of the crystallization from aqueous solutions: The example of aluminum oxy(hydroxi)des and aluminosilicates

Abstract : This overview features the chemical background on condensation phenomena of the aluminum cation in aqueous solution. The formation of polycationic molecular clusters and nanosized solid phases of aluminum oxy(hydroxi)des is interpreted with illustrative mechanisms, building a bridge between solution chemistry and solid-state chemistry. The formation of the main structural types of aluminosilicates (zeolites, clays, imogolite) is also illustrated through the aqueous chemistry of aluminum and silicates.
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https://hal.sorbonne-universite.fr/hal-02354000
Contributor : Olivier Durupthy <>
Submitted on : Thursday, November 7, 2019 - 3:29:18 PM
Last modification on : Saturday, September 19, 2020 - 4:36:11 AM

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Jean-Pierre Jolivet, Corinne Chanéac, David Chiche, Sophie Cassaignon, Olivier Durupthy, et al.. Basic concepts of the crystallization from aqueous solutions: The example of aluminum oxy(hydroxi)des and aluminosilicates. Comptes Rendus Géoscience, Elsevier Masson, 2011, 343 (2-3), pp.113-122. ⟨10.1016/j.crte.2010.12.006⟩. ⟨hal-02354000⟩

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