Investigation of polymer-derived Si–(B)–C–N ceramic/reduced graphene oxide composite systems as active catalysts towards the hydrogen evolution reaction - Sorbonne Université Access content directly
Journal Articles Scientific Reports Year : 2020

Investigation of polymer-derived Si–(B)–C–N ceramic/reduced graphene oxide composite systems as active catalysts towards the hydrogen evolution reaction

Jonathan Barés
Mikhael Bechelany
Damien Voiry
Chrystelle Salameh

Abstract

Hydrogen Evolution Reaction (HER) is an attractive technology for chemical conversion of energy. Replacement of platinum with inexpensive and stable electrocatalysts remains a major bottleneck hampering large-scale hydrogen production by using clean and renewable energy sources. Here, we report electrocatalytically active and ultra-stable Polymer-Derived Ceramics towards HER. We successfully prepared ultrathin silicon and carbon (Si-C) based ceramic systems supported on electrically conducting 2D reduced graphene oxide (rGO) nanosheets with promising HER activity by varying the nature and the composition of the ceramic with the inclusion of nitrogen, boron and oxygen. Our results suggest that oxygen-enriched Si-B-C-N/rGO composites (O-SiBCN/rGO) display the strongest catalytic activity leading to an onset potential and a Tafel slope of - 340 mV and ~ 120 mV dec-1 respectively. O-SiBCN/rGO electrodes display stability over 170 h with minimal increase of 14% of the overpotential compared to ~ 1700% for commercial platinum nanoparticles. Our study provides new insights on the performance of ceramics as affordable and robust HER catalysts calling for further exploration of the electrocatalytic activity of such unconventional materials.
Fichier principal
Vignette du fichier
2020_Hanniet_Investigation.pdf (4.45 Mo) Télécharger le fichier
2020_Hanniet_Investigation_SI.pdf (1010.15 Ko) Télécharger le fichier
Origin : Publisher files allowed on an open archive

Dates and versions

hal-03145377 , version 1 (18-02-2021)

Licence

Attribution

Identifiers

Cite

Quentin Hanniet, Moustapha Boussmen, Jonathan Barés, Vincent Huon, Igor Iatsunskyi, et al.. Investigation of polymer-derived Si–(B)–C–N ceramic/reduced graphene oxide composite systems as active catalysts towards the hydrogen evolution reaction. Scientific Reports, 2020, 10, pp.22003, 1-15. ⟨10.1038/s41598-020-78558-x⟩. ⟨hal-03145377⟩
139 View
115 Download

Altmetric

Share

Gmail Facebook X LinkedIn More