Supramolecular interactions between β-cyclodextrin and hydrophobically end-capped poly(ethylene glycol)s: A quartz crystal microbalance study - Sorbonne Université Access content directly
Journal Articles Journal of Colloid and Interface Science Year : 2007

Supramolecular interactions between β-cyclodextrin and hydrophobically end-capped poly(ethylene glycol)s: A quartz crystal microbalance study

Abstract

In this study, the supramolecular interactions occurring between β-cyclodextrin-based surfaces and macromolecular chains modified at one end with naphthyl, adamantyl, or phenyladamantyl hydrophobic groups were investigated by means of a quartz crystal microbalance. β-Cyclodextrin-functionalized gold electrodes were obtained through the amide-coupling reaction between mono-6-deoxy-6-amino-β-cyclodextrin and 11-mercaptoundecanoic acid self-assembled monolayer allowing the reproducible preparation of densely grafted surfaces with host properties. The interaction data obtained for the three different modified poly(ethylene glycol)s are in good agreement with our previous studies performed by high performance liquid chromatography and surface plasmon resonance. This evidences that the driving force for the supramolecular interaction is based on the inclusion of the hydrophobic terminal group of the chains within the cyclodextrin cavities. The reversibility of the inclusion process was proven through the regeneration of the original host properties of the sensing surfaces using sodium dodecylsulfate as a competitor for the desorption of the poly(ethylene glycol) chains.

Dates and versions

hal-04152618 , version 1 (05-07-2023)

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Khémara Kham, Mohamed Guerrouache, Benjamin Carbonnier, Mathieu Lazerges, Hubert Perrot, et al.. Supramolecular interactions between β-cyclodextrin and hydrophobically end-capped poly(ethylene glycol)s: A quartz crystal microbalance study. Journal of Colloid and Interface Science, 2007, 315 (2), pp.800-804. ⟨10.1016/j.jcis.2007.06.086⟩. ⟨hal-04152618⟩
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