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Journal Articles Journal of Applied Electrochemistry Year : 1984

Impedance of a porous electrode with an axial gradient of concentration

Abstract

When the impedance is measured on a battery, an inductive impedance is often observed in a high frequency range. This inductance is frequently related to the cell geometry and electrical leads. However, certain authors claimed that this inductance is due to the concentration distribution of reacting species through the pores of battery electrodes. Their argument is based on a paper in which a fundamental error was committed. Hence, the impedance is re-calculated on the basis of the same principle. The model shows that though the diffusion process plays an outstanding role, the overall reaction rate is never completely limited by this process. The faradaic impedance due to the concentration distribution is capacitive. Therefore, the inductive impedance observed on battery systems cannot be, by any means, attributed to the concentration distribution inside the pores. Little frequency distribution is found and the impedance is close to a semi-circle. Therefore depressed impedance diagrams in porous electrodes without forced convection cannot be ascribed to either a Warburg nor a Warburg-de Levie behaviour.

Dates and versions

hal-04665560 , version 1 (31-07-2024)

Identifiers

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Michel Keddam, Christiane Rakotomavo, Hisasi Takenouti. Impedance of a porous electrode with an axial gradient of concentration. Journal of Applied Electrochemistry, 1984, 14 (4), pp.437-448. ⟨10.1007/BF00610808⟩. ⟨hal-04665560⟩
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