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Article Dans Une Revue Electrochimica Acta Année : 2012

An enzymatic biofuel cell based on electrically wired polyphenol oxidase and glucose oxidase operating under physiological conditions

Résumé

This paper reports the development and optimisation of a glucose/O-2 biofuel cell. At the anode, the glucose oxidation was performed by glucose oxidase (GOx) co-immobilised with a phenanthrenequinone mediator. At the cathode, the catalysis of O-2 using tetrathiafulvalene and polyphenol oxidase (PPO) has been demonstrated for the first time. The open circuit voltage (OCV) of the optimised biofuel cell reached 0.32 V, and the maximum power density achieved was 40.811 mu W cm(-2) at 0.2 V. This original new GBFC showed quasi-stability in both OCV and power density for more than 25 days.

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Chimie Autre
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Dates et versions

hal-00797027 , version 1 (24-04-2015)

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Fabien Giroud, Chantal Gondran, Karine Gorgy, Vincent Vivier, Serge Cosnier. An enzymatic biofuel cell based on electrically wired polyphenol oxidase and glucose oxidase operating under physiological conditions. Electrochimica Acta, 2012, 85 (15), pp.278-282. ⟨10.1016/j.electacta.2012.08.072⟩. ⟨hal-00797027⟩
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