This PhD thesis, at the interface between chemistry and physics, uses Solid State Nuclear Magnetic Resonance (ssNMR) for both exploiting diversity of materials and developing new easy-to-implement methodologies. ssNMR has proved to be really efficient to study materials and especially their interface by precisely characterising chemical environment of studied nuclei [1]. However, the main drawback of this technique is its lack of sensitivity, each analysis requiring 30 to 400 mg of sample. Such an amount is particularly difficult to obtain for sol-gel thin-film layers or for biological studies like Kidney stones. In order to solve this issue, the MACS (Magic Angle Coil Spinning) technique has been recently developed [2]. It consists of a micro-scaled coil surrounding a capillary containing the sample. Only 30 to 100 µg of material is necessary. As the microcoil is placed inside the usual solid state NMR rotor, no probe modification is needed. [1] C. Bonhomme, C. Gervais, and D. Laurencin, “Recent NMR developments applied to organic–inorganic materials,” Progress in Nuclear Magnetic Resonance Spectroscopy, vol. 77, pp. 1–48, Feb. 2014. [2] D. Sakellariou, G. L. Goff, and J.-F. Jacquinot, “High-resolution, high-sensitivity NMR of nanolitre anisotropic samples by coil spinning,” Nature, vol. 447, no. 7145, pp. 694–697, Jul. 2007.