Photo-induced cation translocation in a molecular shuttle based on a calix[4]-biscrown including DCM and DMABN chromophores
Abstract
We present a new molecular shuttle, consisting of a calixarene core attached to two different photoactive centers, DCM and DMABN. We show that a K+ ion bound to the DCM-grafted crown is translocated towards the other site of the molecule upon photoexcitation, but not released to the bulk.
Domains
Chemical Sciences
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Dozova_ChemComm_final_MS.pdf (488.34 Ko)
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Dozova_ChemCom_final_ESI.pdf (2.84 Mo)
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Origin : Files produced by the author(s)
Origin : Files produced by the author(s)
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