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Article Dans Une Revue Journal of Chemical Physics Année : 2016

Glass-like dynamics of the strain-induced coil/helix transition on a permanent polymer network

Résumé

We study the stress response to a step strain of covalently bonded gelatin gels in the temperature range where triple helix reversible crosslink formation is prohibited. We observe slow stress relaxation towards a T-dependent finite asymptotic level. We show that this is assignable to the strain-induced coil → helix transition, previously evidenced by Courty et al. [Proc. Natl. Acad. Sci. U. S. A. 102, 13457 (2005)], of a fraction of the polymer strands. Relaxation proceeds, in a first stage, according to a stretched exponential dynamics, then crosses over to a terminal simple exponential decay. The respective characteristic times τK and τf exhibit an Arrhenius-like T-dependence with an associated energyE incompatibly larger than the activation barrier height for the isomerisation process which sets the clock for an elementary coil → helix transformation event. We tentatively assign this glass-like slowing down of the dynamics to the long-range couplings due to the mechanical noise generated by the local elementary events in this random elastic medium.
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Dates et versions

hal-01304263 , version 1 (12-10-2021)

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Olivier Ronsin, C. Caroli, Tristan Baumberger. Glass-like dynamics of the strain-induced coil/helix transition on a permanent polymer network. Journal of Chemical Physics, 2016, 144 (6), pp.064904. ⟨10.1063/1.4941456⟩. ⟨hal-01304263⟩
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