Glass-like dynamics of the strain-induced coil/helix transition on a permanent polymer network - Sorbonne Université Accéder directement au contenu
Article Dans Une Revue The Journal of Chemical Physics Année : 2016

Glass-like dynamics of the strain-induced coil/helix transition on a permanent polymer network

Résumé

We study the stress response to a step strain of covalently bonded gelatin gels in the temperature range where triple helix reversible crosslink formation is prohibited. We observe slow stress relaxation towards a T-dependent finite asymptotic level. We show that this is assignable to the strain-induced coil → helix transition, previously evidenced by Courty et al. [Proc. Natl. Acad. Sci. U. S. A. 102, 13457 (2005)], of a fraction of the polymer strands. Relaxation proceeds, in a first stage, according to a stretched exponential dynamics, then crosses over to a terminal simple exponential decay. The respective characteristic times τK and τf exhibit an Arrhenius-like T-dependence with an associated energyE incompatibly larger than the activation barrier height for the isomerisation process which sets the clock for an elementary coil → helix transformation event. We tentatively assign this glass-like slowing down of the dynamics to the long-range couplings due to the mechanical noise generated by the local elementary events in this random elastic medium.
Fichier principal
Vignette du fichier
1.4941456.pdf (313.69 Ko) Télécharger le fichier
Origine Fichiers produits par l'(les) auteur(s)

Dates et versions

hal-01304263 , version 1 (12-10-2021)

Identifiants

Citer

Olivier Ronsin, C. Caroli, Tristan Baumberger. Glass-like dynamics of the strain-induced coil/helix transition on a permanent polymer network. The Journal of Chemical Physics, 2016, 144 (6), pp.064904. ⟨10.1063/1.4941456⟩. ⟨hal-01304263⟩
117 Consultations
30 Téléchargements

Altmetric

Partager

Gmail Mastodon Facebook X LinkedIn More