Bis-phosphine allene ligand: coordination chemistry and preliminary applications in catalysis
Abstract
A 1,3-bis-diphenylphosphine allene can give rise to new coordination complexes with palladium, platinum and gold metals. These complexes were fully characterized by NMR, HRMS and X-ray diffraction analysis. For gold(I), the corresponding dinuclear complex has been used in a series of diagnostic catalytic reactions and gave promising preliminary results in asymmetric catalysis.
Domains
Chemical Sciences
Origin : Files produced by the author(s)
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