Dehydrogenative Allylic Aminations of But-3-enoic Acid Derivatives - Sorbonne Université
Journal Articles Synthesis: Journal of Synthetic Organic Chemistry Year : 2016

Dehydrogenative Allylic Aminations of But-3-enoic Acid Derivatives

Abstract

Two complementary Pd-catalyzed protocols enabling the γ-selective intermolecular allylic amination of but-3-enoic acid derivatives are reported. These transformations could be successfully achieved via, either a direct Pd(II)-catalyzed protocol or an one-pot Pd(II)/Pd(0)-catalyzed sequence, depending on the nature of the nitrogen nucleophile used.
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Dates and versions

hal-01408962 , version 1 (05-12-2016)

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Daria Diamante, Sara Gabrieli, Tiziana Benincori, Gianluigi Broggini, Julie Oble, et al.. Dehydrogenative Allylic Aminations of But-3-enoic Acid Derivatives. Synthesis: Journal of Synthetic Organic Chemistry, 2016, 48 (19), pp.3400 - 3412. ⟨10.1055/s-0035-1562453⟩. ⟨hal-01408962⟩
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