Controls on Trace Element Distribution in Oxides and Silicates - Sorbonne Université Accéder directement au contenu
Article Dans Une Revue Journal of Petrology Année : 2018

Controls on Trace Element Distribution in Oxides and Silicates

Résumé

Understanding and quantifying the partitioning of elements at low concentrations is important for petrology, as minor and trace elements are used as tracers of many geological processes. The lattice strain model has consequently been found to be very useful, as it links mineral/melt partition coefficients to the elastic properties of the mineral and to the difference in ionic radius between the trace element and the cation it replaces. However, this model has limitations, particularly in terms of describing crystal strain, due to the form of the equation and from the choice of a hard-sphere model. After a review of the thermodynamics of trace element incorporation into crystal sites and equilibrium between mineral phases, we present classical atomistic modelling using transferable empirical potentials. Following incorporation of one (or more) mismatching element(s), crystal strain appears strongly related to the environment of the site of exchange, with anisotropic, vacancy-rich minerals deforming more than densely-packed minerals, due to anisotropic deformation, rotation and tilting of the surrounding polyhedra. As shown by the computed cation–oxygen length in strained crystal sites, bond strain is smaller than the difference in cation radii, and varies between structures, with densely-packed minerals being less strained. Consequently, computed relaxation energies are smaller in less compressible minerals. This has implications for modelling the partitioning of trace elements, and highlights the limits of using continuum mechanics below crystal cell scale. Neither oxides nor silicates have isotropic elastic properties, and at nanoscale they do not deform like continuous material. Predictions of partitioning between mineral and melt (or fluid) remain hampered by several factors, amongst which are (i) knowledge of the thermodynamics properties of the dissolved species (in melts and fluids); (ii) the precision of estimated defect and strain energies; and (iii) the presence of solid solution in natural systems, even when limited to a few percent. The latter may have orders-of-magnitude effects on the calculated partition coefficients due to interactions between strain fields around minor cations, leading to a chemical mixing regime at low concentration different from solid solutions where phase components are found in high proportions. Partitioning between mineral phases in an assemblage is described with similar equations as for mineral/liquid equilibria. In cases where terms linked to fluid species disappear, such as incorporation with similar substitutions in two minerals, the assumption that crystal strain energy is the preponderant term during cation exchange becomes unnecessary and it is preferable to use defect energies rather than strain energies. Application and discussion of these concepts are presented for mineral/melt partitioning and for partitioning between minerals, using garnet/clinopyroxene equilibria. The advantage of atomistic modelling is that it does not rely on fitting. Agreement with experimental data shows predictive accuracy within an order of magnitude, which is poorer than what may be achieved by fitting the lattice strain model to experimental data, but validating the theoretical approach and sufficient for application to some petrology problems. Improvements of the modelling for better application to minerals like augite involve systematic work on the effect of solid solutions on the strain field around defects and imply solving ordering problems.
Fichier principal
Vignette du fichier
Dubacq et Plunder - 2018 - Controls on Trace Element Distribution in Oxides a.pdf (1.68 Mo) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)
Loading...

Dates et versions

hal-02187130 , version 1 (17-07-2019)

Identifiants

Citer

Benoît Dubacq, Alexis Plunder. Controls on Trace Element Distribution in Oxides and Silicates. Journal of Petrology, 2018, 59 (2), pp.233-256. ⟨10.1093/petrology/egy027⟩. ⟨hal-02187130⟩
27 Consultations
125 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More