Carbonyl-Inserted Organo-Hybrids of a Dawson-Type Phosphovanadotungstate: Scope and Chemoselective Oxidation Catalysis - Sorbonne Université Access content directly
Journal Articles Organic Letters Year : 2011

Carbonyl-Inserted Organo-Hybrids of a Dawson-Type Phosphovanadotungstate: Scope and Chemoselective Oxidation Catalysis

Abstract

The Dawson-type polyoxometalate (POM) [P2V3W15O62]9- is a prototype for inclusion of carbonyls of amides, ureas, carbamates, and thiocarbamates into polyoxometallic structures. The carbonyl-inserted POMs catalyze the oxidation of sulfides. Chemoselectivity depends primarily on the proton content of the POM, but it is also influenced by the organic substituent.
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hal-04138046 , version 1 (22-06-2023)

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Julie Oble, Benoît Riflade, Amandine Noël, Max Malacria, Serge Thorimbert, et al.. Carbonyl-Inserted Organo-Hybrids of a Dawson-Type Phosphovanadotungstate: Scope and Chemoselective Oxidation Catalysis. Organic Letters, 2011, 13 (22), pp.5990-5993. ⟨10.1021/ol202430e⟩. ⟨hal-04138046⟩
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