Investigating the Mukaiyama-type epoxidation reaction of alkenes with Cr(III) salophen catalysts: A confrontation between experiments and DFT calculations
Résumé
This study aimed at the complete elucidation of the mechanism of the Mukaiyama-type alkene epoxidation reaction using the [(salophen)CrIIICl] precatalyst, by combining spectroscopic (UV–visible and EPR) studies, catalytic reactivity and quantum chemical modeling. These studies performed in parallel allowed us to propose a detailed reaction scheme, in which two consecutive active species incorporating both {salophen(CrV = O)} moieties were formed in situ, resulting in two distinct catalytic regimes.