Investigation of magnetic effects on mass transport at the electrode/electrolyte interface by impedance techniques
Résumé
Considerable progress has been made concerning the interpretation of the
combined effect of electric and magnetic fields in electrolyte solution [l-4]. It was
shown on the basis of the Boltzmann equation that the ionic mobility and the
thermal and mass-diffusion coefficients are magnetic field-dependent tensorial
quantities. In recent years, interest has been directed increasingly to magnetoelec-
trolysis, i.e. the effect of a magnetic field in electrochemistry, either for academic
purposes or in view of practical applications [5-141. A comprehensive review
including an extensive bibliography has been published recently [15].
In particular, the effect of a magnetic field on the mass transport phenomena
involved in a reaction mechanism occurring at an electrode/electrolyte interface has
been investigated. According to the works published, a magnetic field coupled with
an electric field can generate solution streams, thereby reducing the boundary layer
thickness and consequently improving the mass transport rate. Previous authors
have observed a variation of the limiting current proportional to B113 or B”* when
the magnetic field density B is changed, following the geometry and the experimen-
tal conditions [6]. They have also noticed an influence of the orientation of the
magnetic field. The enhancement of the limiting current by an imposed magnetic
field is generally interpreted as the consequence of a magnetohydrodynamic (MHD)
effect.