Ultrafast nuclear dynamics in double-core-ionized water molecules
Iyas Ismail
(1)
,
Ludger Inhester
(2)
,
Tatiana Marchenko
(1)
,
Florian Trinter
(3, 4)
,
Abhishek Verma
(1)
,
Alberto de Fanis
(5)
,
Anthony Ferté
(1)
,
Daniel Rivas
(5)
,
Dawei Peng
(1, 5)
,
Dimitris Koulentianos
(6)
,
Edwin Kukk
(1, 7)
,
Francis Penent
(1)
,
Gilles Doumy
(6)
,
Giuseppe Sansone
(8)
,
John Bozek
(9)
,
Kai Li
(6, 10)
,
Linda Young
(6, 10)
,
Markus Ilchen
(5)
,
Maria Novella Piancastelli
(1)
,
Michael Meyer
(5)
,
Nicolas Velasquez
(1)
,
Oksana Travnikova
(1)
,
Rebecca Boll
(5)
,
Renaud Guillemin
(1)
,
Reinhard Dörner
(3)
,
Richard Taïeb
(1)
,
Simon Dold
(3)
,
Stéphane Carniato
(1)
,
Thomas Baumann
(5)
,
Tommaso Mazza
(5)
,
Yevheniy Ovcharenko
(5)
,
Ralph Püttner
(11)
,
Marc Simon
(1)
1
LCPMR -
Laboratoire de Chimie Physique - Matière et Rayonnement
2 DESY - Deutsches Elektronen-Synchrotron [Hamburg]
3 Goethe-Universität Frankfurt am Main
4 FHI - Fritz-Haber-Institut der Max-Planck-Gesellschaft
5 European XFEL Gmbh
6 ANL - Argonne National Laboratory [Lemont]
7 University of Turku
8 Albert-Ludwigs-Universität Freiburg = University of Freiburg
9 SSOLEIL - Synchrotron SOLEIL
10 James Franck Institute
11 Freie Universität Berlin
2 DESY - Deutsches Elektronen-Synchrotron [Hamburg]
3 Goethe-Universität Frankfurt am Main
4 FHI - Fritz-Haber-Institut der Max-Planck-Gesellschaft
5 European XFEL Gmbh
6 ANL - Argonne National Laboratory [Lemont]
7 University of Turku
8 Albert-Ludwigs-Universität Freiburg = University of Freiburg
9 SSOLEIL - Synchrotron SOLEIL
10 James Franck Institute
11 Freie Universität Berlin
Iyas Ismail
- Fonction : Auteur
- PersonId : 756045
- ORCID : 0000-0003-2007-6419
- IdRef : 095120327
Ludger Inhester
- Fonction : Auteur
- PersonId : 1170529
- ORCID : 0000-0003-1417-4151
Tatiana Marchenko
- Fonction : Auteur
- PersonId : 178617
- IdHAL : tatiana-marchenko
- ORCID : 0000-0002-9015-3339
- IdRef : 242168469
Oksana Travnikova
- Fonction : Auteur
- PersonId : 741834
- IdHAL : oksana-travnikova
- ORCID : 0000-0001-9504-3692
- IdRef : 253125391
Résumé
Double-core-hole (DCH) states in isolated-water and heavy-water molecules, resulting from the sequential absorption of two x-ray photons, have been investigated. A comparison of the subsequent Auger emission spectra from the two isotopes provides direct evidence of ultrafast nuclear motion during the 1.5-fs lifetime of these DCH states. Our numerical results align well with the experimental data, providing for various DCH states an in-depth study of the dynamics responsible of the observed isotope effect.