Mechanical switching of magnetic interaction by tweezers-type complex

A control of the interaction between two spin centers was achieved by using a mechanical motion in a terpy(Cu–salphen)2 complex. Upon coordination a conformation change and switching from a paramagnetic to an antiferromagnetically coupled system was observed by EPR and SQUID measurements.

Domaines

Chimie

Fichier principal

c5cc04980f.pdf (2.58 Mo)

Origine	Publication financée par une institution

HAL SU Administrateur : Connectez-vous pour contacter le contributeur

https://hal.sorbonne-universite.fr/hal-01190834

Soumis le : mardi 1 mars 2016-12:26:57

Dernière modification le : mardi 7 mai 2024-10:46:15

Dates et versions

hal-01190834 , version 1 (01-09-2015)

hal-01190834 , version 2 (01-03-2016)

Licence

Paternité

Identifiants

HAL Id : hal-01190834 , version 2
DOI : 10.1039/C5CC04980F

Citer

Benjamin Doistau, Jean-Louis Cantin, Lise-Marie Chamoreau, Valérie Marvaud, Bernold Hasenknopf, et al.. Mechanical switching of magnetic interaction by tweezers-type complex. Chemical Communications, 2015, 51 (65), pp.12916-12919. ⟨10.1039/C5CC04980F⟩. ⟨hal-01190834v2⟩

Exporter

BibTeX XML-TEI Dublin Core DC Terms EndNote DataCite

Collections

UPMC CNRS INSP ALLINSP IPCM INSP-E5 INC-CNRS IPCM-GOBS IPCM-E-POM SORBONNE-UNIVERSITE SU-SCIENCES CHIMIE-SU

172 Consultations

151 Téléchargements